PROJECT

Project ID:  PN-III-P1-1.1-TE-2019-1209

Project Director:  Dr.  Daniel Cristea

Project title: Magnetron sputtered Me-Me binary oxynitride multifunctional thin solid films

Project Type: National

Project Program: HUMAN RESOURCES, Young Teams

Funded by:  Romanian National Authority for Scientific Research, UEFISCDI

Contractor: Transilvania University of Brasov

Project Status: on-going

Start Date: 15 September 2020

End Date: 14 September 2022

 

Background

Binary Me oxynitride-type compounds (Me1Me2OxNy, where Me1, Me2 = Ti, Al, Sr, Nb, Mg, Mo, etc.) have received attention in recent years due to their original properties compared to their oxide or nitride parents. For example, the decrease of the band-gap consecutive of the nitrogen substitution for oxygen in the perovskite (Me1Me2O3) structure leads to an absorption in the visible domain, with potential applications as pigments and visible photocatalysts, for instance, in overall water splitting reactions. Other applications which have been proposed are mostly related to high-temperature solar selective absorbing coatings for parabolic trough concentrated solar power (CSP) photo-thermal conversion: NbTiON; WAlON, NbAlON, NbMoON, all with the same purpose (absorbing layers). Furthermore, NbAlON was proposed as a superconductive material. TiAlON films were reported to be potentially used as corrosion resistant films, as dark decorative coatings, as oxidation and wear resistant dry cutting tool coatings, as high temperature miniaturized strain gauges, as absorber layers for photo-thermal conversion multilayers. The multitude of possible applications for Me1Me2OxNy-type materials stems from the numerous types of structures that can arise, controllable through the processing parameters (deposition, thermal annealing, etc.).

 sputtering

This work is supported by a grant of the Romanian Ministry of Education and Research, CNCS - UEFISCDI, project number PN-III-P1-1.1-TE-2019-1209, within PNCDI III.